Poly[(μ6-6-oxidopyridinium-2-carboxylato)caesium]
نویسندگان
چکیده
The asymmetric unit of the polymeric title salt, [Cs(C(6)H(4)NO(3))](n), comprises a Cs(+) cation and a 6-oxidopyridinium-2-carboxyl-ate anion. The Cs(+) cation is six-coordinated by O atoms derived from two oxido and four carboxyl-ate O atoms; each O atom in the anion bridges two Cs(+) cations. In the crystal, inter-molecular N-H⋯O hydrogen bonding is present and contributes to the stability of the three-dimensional network generated by the bridging O atoms.
منابع مشابه
catena-Poly[[tetraaquamanganese(II)]-μ-5-carboxylato-1-carboxylatomethyl-2-oxidopyridinium-κ2 O 5:O 1]
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متن کاملBis(μ-5-carboxylato-1-carboxylatomethyl-2-oxidopyridinium)-κ2 O 5:O 1;κ2 O 1:O 5-[diaqua(phenanthroline-κ2 N,N′)manganese(II)] dihydrate
The centrosymmetric binuclear title complex, [Mn(2)(C(8)H(5)NO(5))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)]·2H(2)O, was obtained by the reaction of manganese chloride with 5-carb-oxy-1-carboxy-methyl-2-oxidopyridinium and 1,10-phenanthroline. The Mn(II) atom is coordinated by two N atoms from the 1,10-phenanthroline ligand, two O atoms from two 5-carboxyl-ato-1-carboxyl-atomethyl-2-oxidopyridinium ligan...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011